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A Boron Alkylidene-Alkene Cycloaddition Reaction: Application to the Synthesis of Aphanamal

We describe an unusual net 2+2 cycloaddition reaction between boron alkylidenes and unactivated alkenes. This reaction provides a new method for construction of carbocyclic ring systems bearing versatile organoboronic esters. In addition to surveying the scope of this reaction, we provide details ab...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Liu, Xun, Deaton, T. Maxwell, Haeffner, Fredrik, Morken, James P.
Format: Artigo
Idioma:Inglês
Publicat: 2017
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5699471/
https://ncbi.nlm.nih.gov/pubmed/28718214
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705720
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