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Stereoselective Synthesis of Trisubstituted Alkenylboron Reagents by Boron-Wittig Reaction of Ketones

Application of the boron-Wittig reaction to ketone electrophiles provides a straightforward route to trisubstituted alkenylboronic esters. With either pentamethyldiethylenetriamine or trimethyl-1,4,7-triazacyclononane additive, the olefination can occur with very high levels of stereocontrol and in...

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Xehetasun bibliografikoak
Argitaratua izan da:Org Lett
Egile Nagusiak: Namirembe, Sheila, Gao, Chenpeng, Wexler, Ryan P., Morken, James P.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2019
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC7054900/
https://ncbi.nlm.nih.gov/pubmed/31140815
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b01663
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