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Intercepting the Gold‐Catalysed Meyer–Schuster Rearrangement by Controlled Protodemetallation: A Regioselective Hydration of Propargylic Alcohols
The regioselective gold‐catalysed hydration of propargylic alcohols to β‐hydroxy ketones can be achieved by diverting the gold‐catalysed Meyer–Schuster rearrangement through the addition of a protic additive with a pK (a) of 7–9 such as p‐nitrophenol, boric acid or a boronic acid. This provides an i...
Αποθηκεύτηκε σε:
| Τόπος έκδοσης: | Adv Synth Catal |
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| Κύριοι συγγραφείς: | , , , , , , |
| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
John Wiley and Sons Inc.
2016
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5698882/ https://ncbi.nlm.nih.gov/pubmed/29200990 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201600101 |
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