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HBF(4)-Catalysed Nucleophilic Substitutions of Propargylic Alcohols

The activity of HBF(4) (aqueous solution) as a catalyst in propargylation reactions is presented. Diverse types of nucleophiles were employed in order to form new C–O, C–N and C–C bonds in technical acetone and in air. Good to excellent yields and good chemoselectivities were obtained using low acid...

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Detalhes bibliográficos
Publicado no:European J Org Chem
Main Authors: Barreiro, Elena, Sanz-Vidal, Alvaro, Tan, Eric, Lau, Shing-Hing, Sheppard, Tom D, Díez-González, Silvia
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4676292/
https://ncbi.nlm.nih.gov/pubmed/26693210
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201501249
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