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Synthesis and Utilization of Nitroalkyne Equivalents in Batch and Continuous Flow

We report a method for overcoming the low stability of nitroalkynes through the development of nitrated vinyl silyltriflate equivalents. Because of their instability, nitroalkynes have only rarely been utilized in synthesis. The reactivity of these silyltriflates, which are prepared in situ, is exem...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Morse, Peter D., Jamison, Timothy F.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2017
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5698803/
https://ncbi.nlm.nih.gov/pubmed/28929565
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706157
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