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Radical‐Based C−C Bond‐Forming Processes Enabled by the Photoexcitation of 4‐Alkyl‐1,4‐dihydropyridines

We report herein that 4‐alkyl‐1,4‐dihydropyridines (alkyl‐DHPs) can directly reach an electronically excited state upon light absorption and trigger the generation of C(sp(3))‐centered radicals without the need for an external photocatalyst. Selective excitation with a violet‐light‐emitting diode tu...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Buzzetti, Luca, Prieto, Alexis, Roy, Sudipta Raha, Melchiorre, Paolo
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5698711/
https://ncbi.nlm.nih.gov/pubmed/28984403
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201709571
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