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Radical‐Based C−C Bond‐Forming Processes Enabled by the Photoexcitation of 4‐Alkyl‐1,4‐dihydropyridines
We report herein that 4‐alkyl‐1,4‐dihydropyridines (alkyl‐DHPs) can directly reach an electronically excited state upon light absorption and trigger the generation of C(sp(3))‐centered radicals without the need for an external photocatalyst. Selective excitation with a violet‐light‐emitting diode tu...
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| Publicat a: | Angew Chem Int Ed Engl |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
John Wiley and Sons Inc.
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5698711/ https://ncbi.nlm.nih.gov/pubmed/28984403 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201709571 |
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