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Radical‐Based C−C Bond‐Forming Processes Enabled by the Photoexcitation of 4‐Alkyl‐1,4‐dihydropyridines

We report herein that 4‐alkyl‐1,4‐dihydropyridines (alkyl‐DHPs) can directly reach an electronically excited state upon light absorption and trigger the generation of C(sp(3))‐centered radicals without the need for an external photocatalyst. Selective excitation with a violet‐light‐emitting diode tu...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Buzzetti, Luca, Prieto, Alexis, Roy, Sudipta Raha, Melchiorre, Paolo
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2017
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5698711/
https://ncbi.nlm.nih.gov/pubmed/28984403
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201709571
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