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Traversing Biosynthetic Carbocation Landscapes in the Total Synthesis of Andrastin and Terretonin Meroterpenes

Meroterpenes derived from dimethylorsellinic acid (DMOA) and farnesyl pyrophosphate have attracted much biosynthetic attention, yet only recently have synthetic solutions to any family members appeared. A key point of divergence in DMOA-derived meroterpene biosynthesis is the protoaustinoid A carboc...

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Detalles Bibliográficos
Publicado en:Angew Chem Int Ed Engl
Main Authors: Xu, Gong, Elkin, Masha, Tantillo, Dean J., Newhouse, Timothy R., Maimone, Thomas J.
Formato: Artigo
Idioma:Inglês
Publicado: 2017
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5697905/
https://ncbi.nlm.nih.gov/pubmed/28799296
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705654
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