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Secondary Carbocations in the Biosynthesis of Pupukeanane Sesquiterpenes

The results of quantum chemical calculations on putative biosynthetic carbocation cyclization/rearrangements leading to pupukeanane and related sesquiterpenes indicate that a secondary carbocation proposed as an intermediate is not a minimum on the potential energy surface and instead resides in a r...

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Bibliografiska uppgifter
I publikationen:J Phys Chem A
Huvudupphovsmän: McCulley, Christina H., Tantillo, Dean J.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2018
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC6311099/
https://ncbi.nlm.nih.gov/pubmed/30209949
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.8b07961
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