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Secondary Carbocations in the Biosynthesis of Pupukeanane Sesquiterpenes
The results of quantum chemical calculations on putative biosynthetic carbocation cyclization/rearrangements leading to pupukeanane and related sesquiterpenes indicate that a secondary carbocation proposed as an intermediate is not a minimum on the potential energy surface and instead resides in a r...
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| Veröffentlicht in: | J Phys Chem A |
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| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6311099/ https://ncbi.nlm.nih.gov/pubmed/30209949 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.8b07961 |
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