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Traversing Biosynthetic Carbocation Landscapes in the Total Synthesis of Andrastin and Terretonin Meroterpenes

Meroterpenes derived from dimethylorsellinic acid (DMOA) and farnesyl pyrophosphate have attracted much biosynthetic attention, yet only recently have synthetic solutions to any family members appeared. A key point of divergence in DMOA-derived meroterpene biosynthesis is the protoaustinoid A carboc...

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Dades bibliogràfiques
Publicat a:Angew Chem Int Ed Engl
Autors principals: Xu, Gong, Elkin, Masha, Tantillo, Dean J., Newhouse, Timothy R., Maimone, Thomas J.
Format: Artigo
Idioma:Inglês
Publicat: 2017
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5697905/
https://ncbi.nlm.nih.gov/pubmed/28799296
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705654
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