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Direct, Mild, and General n-Bu(4)NBr-Catalyzed Aldehyde Allylsilylation with Allyl Chlorides
A direct, mild, and general method for the enantioselective allylsilylation of aldehydes with allyl chlorides is reported. The reactions are effectively catalyzed by 5 mol% of n-Bu(4)NBr, and this rate acceleration allows the use of complex allyl donors in fragment-coupling reactions and of electron...
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| Publicado no: | Org Lett |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5693333/ https://ncbi.nlm.nih.gov/pubmed/29068688 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b03193 |
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