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Is the tungsten(IV) complex (NEt(4))(2)[WO(mnt)(2)] a functional analogue of acetylene hydratase?
The tungsten(IV) complex (Et(4)N)(2)[W(O)(mnt)(2)] (1; mnt = maleonitriledithiolate) was proposed (Sarkar et al., J. Am. Chem. Soc. 1997, 119, 4315) to be a functional analogue of the active center of the enzyme acetylene hydratase from Pelobacter acetylenicus, which hydrates acetylene (ethyne; 2) t...
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| Publicado no: | Beilstein J Org Chem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5687055/ https://ncbi.nlm.nih.gov/pubmed/29181113 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.230 |
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