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Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non-C(2) Symmetric Digold Catalysts
[Image: see text] The enantioselective intermolecular gold(I)-catalyzed [2+2] cycloaddition of terminal alkynes and alkenes has been achieved using non-C(2)-chiral Josiphos digold(I) complexes as catalysts, by the formation of the monocationic complex. This new approach has been applied to the enant...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
American Chemical
Society
2017
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| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5679663/ https://ncbi.nlm.nih.gov/pubmed/28922911 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07651 |
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