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C(2)-Symmetric Dinickel Catalysts for Enantioselective [4 + 1]-Cycloadditions

Dinickel naphthyridine–bis(oxazoline) catalysts promote enantioselective intermolecular [4 + 1]-cycloadditions of vinylidene equivalents and 1,3-dienes. The products of this reaction are methylenecyclopentenes, and the exocyclic alkene is generally obtained with high Z selectivity. E and Z dienes re...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Behlen, Michael J., Uyeda, Christopher
Format: Artigo
Jezik:Inglês
Izdano: 2020
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7698671/
https://ncbi.nlm.nih.gov/pubmed/32972140
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c08262
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