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Configurational entropy measurements in extremely supercooled liquids that break the glass ceiling

Liquids relax extremely slowly on approaching the glass state. One explanation is that an entropy crisis, because of the rarefaction of available states, makes it increasingly arduous to reach equilibrium in that regime. Validating this scenario is challenging, because experiments offer limited reso...

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Vydáno v:Proc Natl Acad Sci U S A
Hlavní autoři: Berthier, Ludovic, Charbonneau, Patrick, Coslovich, Daniele, Ninarello, Andrea, Ozawa, Misaki, Yaida, Sho
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2017
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5664510/
https://ncbi.nlm.nih.gov/pubmed/29073056
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1706860114
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