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Remote stereoselective deconjugation of α,β-unsaturated esters by simple amidation reactions
The thermodynamically disfavored isomerization of α,β-unsaturated esters to deconjugated β,γ-unsaturated analogues occurs readily when coupled to an amidation. Within the framework of macrocyclic derivatives, it is shown that 15, 16, and 18 membered macrocycles react with tBuOK and anilines to gener...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5664367/ https://ncbi.nlm.nih.gov/pubmed/29142723 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01118c |
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