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Spontaneous head-to-tail cyclization of unprotected linear peptides with the KAHA ligation

The α-ketoacid–hydroxylamine (KAHA) ligation with 5-oxaproline enables the direct cyclization of peptides upon cleavage from a solid support, without coupling reagents, protecting groups, or purification of the linear precursors. This Fmoc SPPS-based method was applied to the synthesis of a library...

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Vydáno v:Chem Sci
Hlavní autoři: Rohrbacher, Florian, Deniau, Gildas, Luther, Anatol, Bode, Jeffrey W.
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2015
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5664356/
https://ncbi.nlm.nih.gov/pubmed/29142720
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01774b
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