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Catalytic Divergent [3+3]- and [3+2]-Cycloaddition by Discrimination Between Diazo Compounds

Highly selective divergent cycloaddition reactions of enoldiazo compounds and α-diazocarboximides catalyzed by copper(I) or dirhodium(II) have been developed. With tetrakis(acetonitrile)copper(I) tetrafluoroborate as the catalyst epoxypyrrolo[1,2-a]azepine derivatives were prepared in good yields an...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Deng, Yongming, Massey, Lynée A., Rodriguez Núñez, Yeray A., Arman, Hadi, Doyle, Michael P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5660928/
https://ncbi.nlm.nih.gov/pubmed/28759139
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706639
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