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Fluoride binding to an organoboron wire controls photoinduced electron transfer

We demonstrate that the rates for long-range electron transfer can be controlled actively by tight anion binding to a rigid rod-like molecular bridge. Electron transfer from a triarylamine donor to a photoexcited Ru(bpy)(3)(2+) acceptor (bpy = 2,2′-bipyridine) across a 2,5-diboryl-1,4-phenylene brid...

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Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Chen, Jing, Wenger, Oliver S.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5659175/
https://ncbi.nlm.nih.gov/pubmed/29511520
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00964b
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