Metallofullerene photoswitches driven by photoinduced fullerene-to-metal electron transfer

We report on the discovery and detailed exploration of the unconventional photo-switching mechanism in metallofullerenes, in which the energy of the photon absorbed by the carbon cage π-system is transformed to mechanical motion of the endohedral cluster accompanied by accumulation of spin density o...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Zalibera, Michal, Ziegs, Frank, Schiemenz, Sandra, Dubrovin, Vasilii, Lubitz, Wolfgang, Savitsky, Anton, Deng, Shihu H. M., Wang, Xue-Bin, Avdoshenko, Stanislav M., Popov, Alexey A.
Format: Artigo
Language:Inglês
Published: The Royal Society of Chemistry 2021
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8188499/
https://ncbi.nlm.nih.gov/pubmed/34168836
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc07045a
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