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Ultrafast photoinduced electron transfer in face-to-face charge-transfer π-complexes of planar porphyrins and hexaazatriphenylene derivatives
Charge-transfer (CT) π-complexes are formed between planar porphyrins and 1,4,5,8,9,12-hexaazatriphenylene (HAT) derivatives with large formation constants (e.g., 10(4) M(–1)), exhibiting broad CT absorption bands. The unusually large formation constants result from close face-to-face contact betwee...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2015
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5630025/ https://ncbi.nlm.nih.gov/pubmed/29308129 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02787f |
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