Ultrafast photoinduced electron transfer in face-to-face charge-transfer π-complexes of planar porphyrins and hexaazatriphenylene derivatives

Charge-transfer (CT) π-complexes are formed between planar porphyrins and 1,4,5,8,9,12-hexaazatriphenylene (HAT) derivatives with large formation constants (e.g., 10(4) M(–1)), exhibiting broad CT absorption bands. The unusually large formation constants result from close face-to-face contact betwee...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Aoki, Toru, Sakai, Hayato, Ohkubo, Kei, Sakanoue, Tomo, Takenobu, Taishi, Fukuzumi, Shunichi, Hasobe, Taku
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5630025/
https://ncbi.nlm.nih.gov/pubmed/29308129
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02787f
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