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Copper-catalyzed intermolecular C(sp(3))–H bond functionalization towards the synthesis of tertiary carbamates

We describe the development of an intermolecular unactivated C(sp(3))–H bond functionalization towards the direct synthesis of tertiary carbamates. The transformation proceeded using a readily available, abundant first-row transition metal catalyst (copper), and isocyanates as the source of the amid...

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Publicat a:Chem Sci
Autors principals: Chikkade, Prasanna Kumara, Kuninobu, Yoichiro, Kanai, Motomu
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2015
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5657409/
https://ncbi.nlm.nih.gov/pubmed/29142689
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00238a
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