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Mechanistic Duality in Tertiary Amine Additions to Thermally Generated (HDDA) Benzynes
Reported here are studies directed at understanding the mechanism of tertiary amine addition to hexade-hydro-Diels-Alder (HDDA)-generated benzynes. Tertiary amines are presumed to engage benzynes by generation of a zwitterionic intermediate. Simple trialkylamines undergo intermolecular protonation b...
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| Publicat a: | Org Lett |
|---|---|
| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5650509/ https://ncbi.nlm.nih.gov/pubmed/28981290 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b02888 |
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