Chargement en cours...
Asymmetric Protonation of Cumulenolates: Synthesis of Allenyl Aldehydes Facilitated by an Organomanganese Auxiliary
Chiral ammonium salts were used to catalyze the isomerization of organomanganese-complexed alkynyl aldehydes to chiral allenal building blocks in moderate to good enantiomeric excesses. Normally, conjugated alkynyl aldehydes do not isomerize to their thermodynamically less stable allene isomers. How...
Enregistré dans:
| Publié dans: | Org Lett |
|---|---|
| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2016
|
| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5649623/ https://ncbi.nlm.nih.gov/pubmed/26925611 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b03681 |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|