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Tetranuclear Manganese Models of the OEC Displaying Hydrogen Bonding Interactions: Application to Electrocatalytic Water Oxidation to Hydrogen Peroxide

Toward the development of structural and functional models of the oxygen evolving complex (OEC) of photosystem II (PSII), we report the synthesis of site-differentiated tetranuclear manganese complexes featuring three six-coordinate and one five-coordinate Mn centers. To incorporate biologically rel...

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Veröffentlicht in:J Am Chem Soc
Hauptverfasser: Han, Zhiji, Horak, Kyle T., Lee, Heui Beom, Agapie, Theodor
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2017
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5643074/
https://ncbi.nlm.nih.gov/pubmed/28587453
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03044
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