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Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes
[Image: see text] Monosubstituted cycloalkanes undergo regio- and enantioselective aliphatic C–H oxidation with H(2)O(2) catalyzed by biologically inspired manganese catalysts. The reaction furnishes the corresponding ketones resulting from oxidation at C3 and C4 methylenic sites (K(3) and K(4), res...
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| Publicado no: | ACS Cent Sci |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2017
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5364455/ https://ncbi.nlm.nih.gov/pubmed/28386597 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.6b00368 |
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