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Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes

[Image: see text] Monosubstituted cycloalkanes undergo regio- and enantioselective aliphatic C–H oxidation with H(2)O(2) catalyzed by biologically inspired manganese catalysts. The reaction furnishes the corresponding ketones resulting from oxidation at C3 and C4 methylenic sites (K(3) and K(4), res...

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Bibliografiset tiedot
Julkaisussa:ACS Cent Sci
Päätekijät: Milan, Michela, Bietti, Massimo, Costas, Miquel
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: American Chemical Society 2017
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC5364455/
https://ncbi.nlm.nih.gov/pubmed/28386597
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.6b00368
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