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Tetranuclear Manganese Models of the OEC Displaying Hydrogen Bonding Interactions: Application to Electrocatalytic Water Oxidation to Hydrogen Peroxide

Toward the development of structural and functional models of the oxygen evolving complex (OEC) of photosystem II (PSII), we report the synthesis of site-differentiated tetranuclear manganese complexes featuring three six-coordinate and one five-coordinate Mn centers. To incorporate biologically rel...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Han, Zhiji, Horak, Kyle T., Lee, Heui Beom, Agapie, Theodor
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5643074/
https://ncbi.nlm.nih.gov/pubmed/28587453
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03044
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