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Cobalt-catalysed reductive C–H alkylation of indoles using carboxylic acids and molecular hydrogen
The direct CH-alkylation of indoles using carboxylic acids is presented for the first time. The catalytic system based on the combination of Co(acac)(3) and 1,1,1-tris(diphenylphosphinomethyl)-ethane (Triphos, L1), in the presence of Al(OTf)(3) as co-catalyst, is able to perform the reductive alkyla...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5632795/ https://ncbi.nlm.nih.gov/pubmed/29163930 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02117h |
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