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Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions

The first general and efficient non-noble metal-catalysed reductive C2-alkoxylation of cyclic imides (phthalimides and succinimides) is presented. Crucial for the success is the use of [Co(BF(4))(2)·6H(2)O/triphos (L1)] combination and no external additives are required. Using the optimal cobalt-sys...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Cabrero-Antonino, Jose R., Adam, Rosa, Papa, Veronica, Holsten, Mattes, Junge, Kathrin, Beller, Matthias
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5618770/
https://ncbi.nlm.nih.gov/pubmed/28970933
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01175j
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