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Micellar catalysis-enabled sustainable ppm Au-catalyzed reactions in water at room temperature

Several ppm level gold-catalyzed reactions enabled by the ligand HandaPhos can be performed at room temperature in aqueous nanoreactors composed of the surfactant Nok. Variously substituted allenes undergo cycloisomerization leading to heterocyclic products in good yields. Likewise, cyclodehydration...

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Publicado en:Chem Sci
Main Authors: Klumphu, Piyatida, Desfeux, Camille, Zhang, Yitao, Handa, Sachin, Gallou, Fabrice, Lipshutz, Bruce H.
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2017
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5628599/
https://ncbi.nlm.nih.gov/pubmed/28989668
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02405c
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