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Sustainable ppm level palladium-catalyzed aminations in nanoreactors under mild, aqueous conditions
A 1 : 1 Pd : ligand complex, [t-BuXPhos(Pd-π-cinnamyl)]OTf, has been identified as a highly robust pre-catalyst for amination reactions leading to diarylamines, where loadings of metal are typically at 1000 ppm Pd, run in water at temperatures between rt and 45 °C. The protocol is exceptionally simp...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Royal Society of Chemistry
2019
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7020654/ https://ncbi.nlm.nih.gov/pubmed/32110341 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03710a |
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