Investigation of the mechanism of the SpnF-catalyzed [4+2]-cycloaddition reaction in the biosynthesis of spinosyn A

The Diels–Alder reaction is one of the most common methods to chemically synthesize a six-membered carbocycle. While it has long been speculated that the cyclohexene moiety found in many secondary metabolites is also introduced via similar chemistry, the enzyme SpnF involved in the biosynthesis of t...

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Pubblicato in:Proc Natl Acad Sci U S A
Autori principali: Jeon, Byung-sun, Ruszczycky, Mark W., Russell, William K., Lin, Geng-Min, Kim, Namho, Choi, Sei-hyun, Wang, Shao-An, Liu, Yung-nan, Patrick, John W., Russell, David H., Liu, Hung-wen
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2017
Soggetti:
Biological Sciences
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5625926/
https://ncbi.nlm.nih.gov/pubmed/28874588
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1710496114
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