Investigation of the mechanism of the SpnF-catalyzed [4+2]-cycloaddition reaction in the biosynthesis of spinosyn A

The Diels–Alder reaction is one of the most common methods to chemically synthesize a six-membered carbocycle. While it has long been speculated that the cyclohexene moiety found in many secondary metabolites is also introduced via similar chemistry, the enzyme SpnF involved in the biosynthesis of t...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Jeon, Byung-sun, Ruszczycky, Mark W., Russell, William K., Lin, Geng-Min, Kim, Namho, Choi, Sei-hyun, Wang, Shao-An, Liu, Yung-nan, Patrick, John W., Russell, David H., Liu, Hung-wen
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2017
Assuntos:
Biological Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5625926/
https://ncbi.nlm.nih.gov/pubmed/28874588
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1710496114
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