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Nickel-catalyzed C–H/N–H annulation of aromatic amides with alkynes in the absence of a specific chelation system
The Ni-catalyzed reaction of aromatic amides with alkynes in the presence of KOBu(t) involves C–H/N–H oxidative annulation to give 1(2H)-isoquinolinones. A key to the success of the reaction is the use of a catalytic amount of strong base, such as KOBu(t). The reaction shows a high functional group...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2017
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5625264/ https://ncbi.nlm.nih.gov/pubmed/28989692 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01750b |
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