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Cobalt-Catalyzed Carbonylative Cross Coupling of Alkyl Tosylates and Dienes: Stereospecific Synthesis of Dienones at Low Pressure
Despite advances in organometallic cross coupling of alkyl electrophiles, there are few stereoselective reactions of chiral, non-racemic substrates. Herein, we report a stereospecific carbonylative coupling of alkyl tosylates and dienes producing enantioenriched dienones. This catalytic process proc...
Enregistré dans:
| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2017
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5623099/ https://ncbi.nlm.nih.gov/pubmed/28829914 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07983 |
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