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Palladium-Catalyzed Alkoxycarbonylation of Unactivated Secondary Alkyl Bromides at Low Pressure

Catalytic carbonylations of organohalides are important C–C bond formations in chemical synthesis. Carbonylations of unactivated alkyl halides remain a challenge, and currently require the use of alkyl iodides under harsh conditions and high pressures of CO. Herein, we report a palladium-catalyzed a...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Sargent, Brendon T., Alexanian, Erik J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5335917/
https://ncbi.nlm.nih.gov/pubmed/27267421
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04610
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