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Manganese-Catalyzed Stereospecific Hydroxymethylation of Alkyl Tosylates

The development of a stereospecific hydroxymethylation of alkyl tosylates using an inexpensive, first-row catalyst is described. The transformation proceeds under mild conditions with low pressure to deliver homologated alcohols as products. Chiral, non-racemic β-branched primary alcohols are obtain...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Shenouda, Hannah, Alexanian, Erik J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7147876/
https://ncbi.nlm.nih.gov/pubmed/31689117
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b03706
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