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Versatile telluracycle synthesis via the sequential electrophilic telluration of C(sp(2))–Zn and C(sp(2))–H bonds

We report herein a new approach for the synthesis of tellurium-bridged aromatic compounds based on the sequential electrophilic telluration of C(sp(2))–Zn and C(sp(2))–H bonds with tellurium(iv) chlorides. A combination of transition metal-catalyzed (migratory) arylmetalation of alkynes and sequenti...

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Publicat a:Chem Sci
Autors principals: Wu, Bin, Melvina, Wu, Xiangyang, Lee Yeow, Edwin Kok, Yoshikai, Naohiko
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2017
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5618338/
https://ncbi.nlm.nih.gov/pubmed/28970880
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01162h
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