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Metal-free direct alkylation of unfunctionalized allylic/benzylic sp(3) C–H bonds via photoredox induced radical cation deprotonation

Despite notable recent efforts, a catalytic and convenient strategy for the direct alkylation of unactivated allylic or benzylic sp(3) C–H bonds remains a formidable challenge facing the synthesis community. We herein report an unprecedented allylic/benzylic alkylation using only an organo-photoredo...

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發表在:Chem Sci
Main Authors: Zhou, Rong, Liu, Haiwang, Tao, Hairong, Yu, Xingjian, Wu, Jie
格式: Artigo
語言:Inglês
出版: Royal Society of Chemistry 2017
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC5618257/
https://ncbi.nlm.nih.gov/pubmed/28970885
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00953d
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