NHC-catalyzed cleavage of vicinal diketones and triketones followed by insertion of enones and ynones

Thiazolium carbene-catalyzed reactions of 1,2-diketones and 1,2,3-triketones with enones and ynones have been investigated. The diketones gave α,β-double acylation products via unique Breslow intermediates isolable as acid salts, whereas the triketones formed stable adducts with the NHC instead of t...

Full description

Saved in:
Bibliographic Details
Published in:Beilstein J Org Chem
Main Authors: Takaki, Ken, Hino, Makoto, Ohno, Akira, Komeyama, Kimihiro, Yoshida, Hiroto, Fukuoka, Hiroshi
Format: Artigo
Language:Inglês
Published: Beilstein-Institut 2017
Subjects:
Full Research Paper
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5588593/
https://ncbi.nlm.nih.gov/pubmed/28904625
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.176
Tags: Add Tag
No Tags, Be the first to tag this record!

Similar Items