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C2-Selective Branched Alkylation of Benzimidazoles by Rhodium(I)-catalyzed C–H Activation
Herein, we report a Rh(I)/bisphosphine/K(3)PO(4) catalytic system allowing for the first time the selective branched C–H alkylation of benzimidazoles with Michael acceptors. Branched alkylation with N,N-dimethyl acrylamide was successfully applied to the alkylation of a broad range of benzimidazoles...
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| Pubblicato in: | J Org Chem |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2017
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5585739/ https://ncbi.nlm.nih.gov/pubmed/28828857 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.7b01723 |
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