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Base-Controlled Completely Selective Linear or Branched Rh(I)-Catalyzed C–H ortho-Alkylation of Azines without Preactivation
A [Rh(I)]/bisphosphine/base catalytic system for the ortho-selective C–H alkylation of azines by acrylates and acrylamides is reported. This catalytic system features an unprecedented complete linear or branched selectivity that is solely dependent on the catalytic base that is used. Complete branch...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5558092/ https://ncbi.nlm.nih.gov/pubmed/28429455 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201702409 |
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