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Base-Controlled Completely Selective Linear or Branched Rh(I)-Catalyzed C–H ortho-Alkylation of Azines without Preactivation
A [Rh(I)]/bisphosphine/base catalytic system for the ortho-selective C–H alkylation of azines by acrylates and acrylamides is reported. This catalytic system features an unprecedented complete linear or branched selectivity that is solely dependent on the catalytic base that is used. Complete branch...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Angew Chem Int Ed Engl |
|---|---|
| Prif Awduron: | , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
2017
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5558092/ https://ncbi.nlm.nih.gov/pubmed/28429455 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201702409 |
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