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Base-Controlled Completely Selective Linear or Branched Rh(I)-Catalyzed C–H ortho-Alkylation of Azines without Preactivation

A [Rh(I)]/bisphosphine/base catalytic system for the ortho-selective C–H alkylation of azines by acrylates and acrylamides is reported. This catalytic system features an unprecedented complete linear or branched selectivity that is solely dependent on the catalytic base that is used. Complete branch...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Angew Chem Int Ed Engl
Egile Nagusiak: Tran, Gaël, Hesp, Kevin D., Mascitti, Vincent, Ellman, Jonathan A.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2017
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC5558092/
https://ncbi.nlm.nih.gov/pubmed/28429455
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201702409
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