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Isolation, structure and reactivity of a scandium boryl oxycarbene complex
The reaction of a half-sandwich scandium boryl complex 1 with CO (1 atm) afforded a novel boryl oxycarbene complex 2. The structure of 2 was characterized by (1)H, (13)C and (11)B NMR, X-ray diffraction, and DFT analysis. Further reaction of 2 with CO (1 atm) yielded a phenylamido- and boryl-substit...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5580044/ https://ncbi.nlm.nih.gov/pubmed/28966773 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03138a |
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