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Ligand Field Strength Mediates Electron Delocalization in Octahedral [((H)L)(2)Fe(6)(L′)(m)](n)(+) Clusters
To assess the impact of terminal ligand binding on a variety of cluster properties (redox delocalization, ground-state stabilization, and breadth of redox state accessibility), we prepared three electron-transfer series based on the hexanuclear iron cluster [((H)L)(2)Fe(6)(L′)(m)](n+) in which the t...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2015
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5572642/ https://ncbi.nlm.nih.gov/pubmed/26231520 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b06453 |
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