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Pd(II)-Catalyzed Site-Selective C(sp(3))–H Alkynylation of Oligopeptides: A Linchpin Approach for Oligopeptide-Drug Conjugation
The palladium(II)-catalyzed C(sp(3))–H alkynylation of oligopeptides was developed with tetrabutylammonium acetate as a key additive. Through molecular design, the acetylene motif serves as a linchpin to introduce a broad range of carbonyl-containing pharmacophores onto oligopeptides, thus providing...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5572133/ https://ncbi.nlm.nih.gov/pubmed/28714148 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706367 |
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